Environmentally friendly process to recover valuable materials from used lithium-ion batteries


ORNL’s green solvent enables environmentally friendly recycling of valuable Li-ion battery materials. Credit: Andy Sproles/ORNL, U.S. Dept. of Energy

Scientists at Oak Ridge National Laboratory have developed a solvent that results in a more environmentally friendly process to recover valuable materials from used lithium-ion batteries, supports a stable domestic supply chain for new batteries and keeps old ones out of landfills.

Spent batteries are typically broken down using smelting, an expensive, energy-intensive process that releases toxic gas. The ORNL-developed alternative is a wet chemical process using triethyl phosphate to dissolve the binder material that adheres cathodes to metal current collectors in Li-ion batteries. The result is efficient recovery of cobalt-based cathodes, graphite and other valuable materials like copper foils that can be repurposed in new batteries.

“With this solvent, we’re able to create a process that reduces toxic exposure for workers and recovers valuable, undamaged, active NMC [nickel-manganese-cobalt] cathodes, clean metal foils and other materials that can be easily reused in new batteries,” said ORNL’s Ilias Belharouak.


New class of cobalt-free cathodes could enhance energy density of next-gen lithium-ion batteries


More information:
Yaocai Bai et al, Recovery of Cathode Materials and Aluminum Foil Using a Green Solvent, ACS Sustainable Chemistry & Engineering (2021). DOI: 10.1021/acssuschemeng.1c01293

Citation:
Environmentally friendly process to recover valuable materials from used lithium-ion batteries (2021, June 2)
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